Monsanto had an ad campaign a bunch of years ago, showing weeds dead in 24 hours after being sprayed. Not true at all. Takes at least a week, more like 2 as others have mentioned. So, they came out with Quik Pro. Quik Pro will kill fast, because of the Diquat in it. But diquat is an old nasty chemical, and I don't like to use it. It's also in a dispersable granule form, which are a pain to mix. You really have to agitate the stuff.
Also, weeds have to be actively growing in order for gly to work. If they're shriveled and half dead already, it just ain't gonna work!
Also also, they die as fast as they grow. If it gets cold, or really dry, and the weeds sorta shut down for a bit but are still green, gly will take longer to work.
Now, for regular little stuff, 2 oz/gallon is fine. For big stuff, vines, 3' tall weeds, etc., go heavier. You can go as high as 12.8oz/gallon and still be on label.
My UDK mix (Ultimate Death Kill) of 8 oz of 41% gly and 2 oz of Three Way Ester II has never failed me.
But, if you're just spraying gly, just be patient.